Fault in PM6 in Prediction of S-Cl(-) non-bonding interaction

 

PM6 predicts that Cl(-) and S=CH2  should combine to form a Cl(-)-S=CH2 complex, with the C-S and S-Cl(-) distances1.6 and 2.3 Angstroms, respectively.  B3LYP and other high-level methods predict the Cl-S distance to be much larger.