SUMMARY OF PM7 CALCULATION, Site No: 23746 MOPAC2016 (Version: 21.055M) Wed Feb 24 15:26:47 2021 No. of days remaining = 365 Empirical Formula: O16 K4 Br4 = 24 atoms MERS=(1,2,1) CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF Potassium perbromate KBrO4) (ICSD 15222) h=-68.8 hr=crc GEOMETRY OPTIMISED USING EIGENVECTOR FOLLOWING (EF). SCF FIELD WAS ACHIEVED HEAT OF FORMATION = -433.75353 KCAL/MOL = -1814.82475 KJ/MOL H.o.F. per unit cell = -108.43838 KCAL, for 4 unit cells, unit cell = O4 K1 Br1 TOTAL ENERGY = -5627.43905 EV ELECTRONIC ENERGY = -11402632.19200 EV CORE-CORE REPULSION = 11397004.75296 EV VOLUME OF UNIT CELL = 197.758 CUBIC ANGSTROMS DENSITY = 3.073 GRAMS/CC A = 7.388 ANGSTROMS B = 3.579 ANGSTROMS C = 7.757 ANGSTROMS ALPHA = 89.831 DEGREES BETA = 90.884 DEGREES GAMMA = 105.369 DEGREES VOLUME OF CLUSTER = 395.51694 ANGSTROMS**3 = 238.186 CM**3/MOLE GRADIENT NORM = 4.35526 = 0.88901 PER ATOM NO. OF FILLED LEVELS = 64 IONIZATION POTENTIAL = 7.499666 EV HOMO LUMO ENERGIES (EV) = -7.500 5.630 MOLECULAR WEIGHT = 731.9996 Pressure required to constrain translation vectors Tv( 25) Pressure: -0.07 GPa Tv( 26) Pressure: -0.09 GPa Tv( 27) Pressure: -0.08 GPa SCF CALCULATIONS = 21 WALL-CLOCK TIME = 2 MINUTES AND 29.297 SECONDS COMPUTATION TIME = 2 MINUTES AND 26.570 SECONDS FINAL GEOMETRY OBTAINED MERS=(1,2,1) CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF Potassium perbromate KBrO4) (ICSD 15222) h=-68.8 hr=crc K 0.46549631 +1 -0.29538678 +1 -0.00580290 +1 K -3.21767501 +1 0.97371347 +1 0.30613473 +1 K -4.03257392 +1 -2.73027782 +1 1.27086241 +1 K -0.35213470 +1 -4.00052630 +1 0.95245840 +1 Br -2.15743644 +1 -2.34866566 +1 -2.25643664 +1 Br -6.60262301 +1 -1.05237052 +1 -1.29966095 +1 Br -1.42375368 +1 -0.66640115 +1 3.51527570 +1 Br 3.02309164 +1 -1.96880163 +1 2.57227243 +1 O -1.04946261 +1 -3.29076811 +1 -3.38898552 +1 O -5.39743631 +1 -0.88699580 +1 -0.25311904 +1 O -2.52482536 +1 0.27437696 +1 4.65153663 +1 O 1.80516655 +1 -2.13363186 +1 1.54112230 +1 O -3.55155766 +1 -3.17300774 +1 -2.92242168 +1 O -7.71284420 +1 -0.12232947 +1 -0.16317596 +1 O -0.02715360 +1 0.15724750 +1 4.17820690 +1 O 4.12564269 +1 -2.89355082 +1 1.43009188 +1 O -2.65882451 +1 -1.67748752 +1 -0.88749193 +1 O -6.29387325 +1 0.15670839 +1 -2.32134810 +1 O -1.44543174 +1 -1.95197957 +1 4.48648626 +1 O 3.44387955 +1 -0.34929816 +1 1.73857643 +1 O -0.93849187 +1 -1.33501850 +1 2.13906454 +1 O 2.72800104 +1 -3.17832994 +1 3.59549869 +1 O -2.12956704 +1 -1.06464622 +1 -3.23049153 +1 O -7.02452868 +1 -2.67230751 +1 -0.46613961 +1 Tv 2.30839570 +1 4.18797202 +1 5.63141337 +1 Tv 0.07603494 +1 4.30330546 +1 -5.72048333 +1 Tv 7.29067659 +1 -2.14837878 +1 -1.54784767 +1