SUMMARY OF PM7 CALCULATION, Site No: 23746 MOPAC2016 (Version: 21.053M) Tue Feb 23 07:48:34 2021 No. of days remaining = 364 Empirical Formula: B8 Cl24 = 32 atoms MERS=(2,2,1) CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF Boron trichloride (BCl3) (ICSD 27869) h=-97 hr=guess GEOMETRY OPTIMISED USING EIGENVECTOR FOLLOWING (EF). SCF FIELD WAS ACHIEVED HEAT OF FORMATION = -914.31141 KCAL/MOL = -3825.47893 KJ/MOL H.o.F. per unit cell = -114.28893 KCAL, for 8 unit cells, unit cell = B1 Cl3 TOTAL ENERGY = -6886.28812 EV ELECTRONIC ENERGY = -31201311.22678 EV CORE-CORE REPULSION = 31194424.93866 EV VOLUME OF UNIT CELL = 159.945 CUBIC ANGSTROMS DENSITY = 2.433 GRAMS/CC A = 5.898 ANGSTROMS B = 5.603 ANGSTROMS C = 8.252 ANGSTROMS ALPHA = 110.126 DEGREES BETA = 43.090 DEGREES GAMMA = 89.523 DEGREES VOLUME OF CLUSTER = 639.78035 ANGSTROMS**3 = 385.284 CM**3/MOLE GRADIENT NORM = 26.61355 = 4.70465 PER ATOM NO. OF FILLED LEVELS = 96 IONIZATION POTENTIAL = 11.047809 EV HOMO LUMO ENERGIES (EV) = -11.048 -1.878 MOLECULAR WEIGHT = 937.3520 Pressure required to constrain translation vectors Tv( 33) Pressure: -0.16 GPa Tv( 34) Pressure: 0.60 GPa Tv( 35) Pressure: 1.73 GPa SCF CALCULATIONS = 24 WALL-CLOCK TIME = 16 MINUTES AND 19.635 SECONDS COMPUTATION TIME = 16 MINUTES AND 11.267 SECONDS FINAL GEOMETRY OBTAINED MERS=(2,2,1) CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF Boron trichloride (BCl3) (ICSD 27869) h=-97 hr=guess B 0.01148990 +1 -0.07575939 +1 -0.28751781 +1 B -3.37505089 +1 2.89505846 +1 0.74084394 +1 Cl -0.00888326 +1 1.63684496 +1 -0.24274009 +1 Cl -2.28294609 +1 3.73346285 +1 1.77215690 +1 Cl 1.11696753 +1 -0.95292013 +1 0.69278402 +1 Cl -3.35025495 +1 1.18234813 +1 0.69057749 +1 Cl -1.07697811 +1 -0.91536297 +1 -1.32165388 +1 Cl -4.48340156 +1 3.77071191 +1 -0.23684625 +1 B 4.02893615 +1 -0.13042897 +1 -4.62629776 +1 B 0.63815683 +1 2.83971386 +1 -3.59873712 +1 Cl 4.00484178 +1 1.58190639 +1 -4.57249421 +1 Cl 1.72533235 +1 3.67973028 +1 -2.56369326 +1 Cl 5.13617421 +1 -1.00914418 +1 -3.65142751 +1 Cl 0.66310071 +1 1.12695471 +1 -3.64446866 +1 Cl 2.93527262 +1 -0.96470474 +1 -5.65842499 +1 Cl -0.46588295 +1 3.71424759 +1 -4.58196306 +1 B -3.55748783 +1 -2.89132366 +1 -3.59587316 +1 B -6.94062707 +1 0.08756212 +1 -2.56995105 +1 Cl -3.57743749 +1 -1.17937795 +1 -3.55443801 +1 Cl -5.85239857 +1 0.92656204 +1 -1.53698345 +1 Cl -2.45147407 +1 -3.76561593 +1 -2.61305834 +1 Cl -6.91889834 +1 -1.62425623 +1 -2.61837899 +1 Cl -4.64272043 +1 -3.73226282 +1 -4.63110129 +1 Cl -8.04556095 +1 0.96532218 +1 -3.55029930 +1 B 0.46918227 +1 -2.93796508 +1 -7.93569984 +1 B -2.91972809 +1 0.04032924 +1 -6.90479266 +1 Cl 0.44225204 +1 -1.22631614 +1 -7.88295479 +1 Cl -1.83167271 +1 0.87661125 +1 -5.86986118 +1 Cl 1.57966291 +1 -3.81543578 +1 -6.96277197 +1 Cl -2.90023172 +1 -1.67130207 +1 -6.95349959 +1 Cl -0.62651317 +1 -3.77330126 +1 -8.96393636 +1 Cl -4.02231258 +1 0.92113180 +1 -7.88459801 +1 Tv 7.98386514 +1 -0.09609535 +1 -8.68188735 +1 Tv -7.12012037 +1 -5.58255541 +1 -6.61270107 +1 Tv 7.68272864 +1 -2.80665148 +1 -1.09095024 +1