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SHIFT=80 PM7 Dimethyl niobium fluoride <Nb-C> <><> <Nb-F> <C-Nb-F> GR=PW91D Nb 0.00000000 +0 0.0000000 +0 0.0000000 +0 0 0 0 C 2.13445400 +1 0.0000000 +0 0.0000000 +0 1 0 0 C 2.05321926 +1 104.1201113 +1 0.0000000 +0 1 2 0 F 1.90561300 +1 118.3626230 +1 133.2005248 +1 1 2 3 H 1.11765107 +1 109.9940300 +1 -125.6616622 +1 2 1 3 H 1.11036182 +1 112.5970574 +1 118.9020046 +1 2 1 5 H 1.11365964 +1 111.7720204 +1 121.8117972 +1 2 1 6 H 1.12885755 +1 111.6434599 +1 125.0380368 +1 3 1 2 H 1.12557605 +1 112.8464517 +1 119.2208542 +1 3 1 8 H 1.12150108 +1 113.7959257 +1 121.8755412 +1 3 1 9