Example of faulty prediction by PM6:

PM6                                                               
  Example of fault in PM6: R-NH2 forms a stable bond with C of R-COO-R                                                              
                                                                                
O       -0.000010 1      0.000000 1      0.000000  1  
H       -0.006153 1      1.804509 1     -1.216513  1  
C        0.793349 1      1.012586 1      0.684446  1  
N        0.710944 1      2.139930 1     -0.545848  1  
H        1.619552 1      2.179397 1     -1.067715  1  
N       -2.484458 1      1.875941 1      0.909176  1  
C       -2.361612 1      0.654350 1      0.060221  1  
C       -3.711812 1     -0.060338 1     -0.054450  1  
H       -2.048603 1      1.013520 1     -0.957498  1  
C       -1.280712 1     -0.332011 1      0.568108  1  
H       -1.200806 1     -0.339978 1      1.669924  1  
H       -1.435439 1     -1.358306 1      0.191631  1  
C        4.701728 1      3.362572 1      1.187370  1  
C        3.766061 1      2.438758 1      0.464656  1  
O        3.521743 1      2.532885 1     -0.737926  1  
N        3.183018 1      1.440377 1      1.233278  1  
C        2.256960 1      0.441744 1      0.647675  1  
O        0.318534 1      1.505194 1      1.728532  1  
C        2.286931 1     -0.860486 1      1.468735  1  
C        3.618933 1     -1.590847 1      1.357470  1  
H        3.611939 1     -2.512902 1      1.950690  1  
H        3.840894 1     -1.871443 1      0.320439  1  
H        2.563594 1      0.227787 1     -0.410142  1  
H        1.462769 1     -1.513616 1      1.101569  1  
H        2.041218 1     -0.649642 1      2.529465  1  
H        3.239406 1      1.447145 1      2.249422  1  
C        0.353784 1      3.528580 1     -0.051939  1  
C        0.976159 1      4.597365 1     -0.934823  1  
H       -0.755833 1      3.628820 1     -0.007715  1  
H        0.703729 1      3.615365 1      1.007640  1  
H       -1.578635 1      2.088017 1      1.356355  1  
H       -3.139763 1      1.725557 1      1.671193  1  
H       -3.683271 1     -0.851277 1     -0.811530  1  
H       -4.499197 1      0.645783 1     -0.352443  1  
H       -4.024534 1     -0.514870 1      0.891475  1  
H        5.512336 1      2.826231 1      1.699090  1  
H        4.182559 1      3.978281 1      1.934734  1  
H        5.176497 1      4.054209 1      0.471391  1  
H        4.454537 1     -0.976932 1      1.712448  1  
H        2.065177 1      4.459131 1     -1.044524  1  
H        0.545532 1      4.613573 1     -1.943006  1  
H        0.821353 1      5.595662 1     -0.505018  1